For water softeners, the evidence is unambiguous. Ion exchange has been the industry standard for domestic water softening for decades. A properly installed and maintained softener eliminates limescale from a hard water supply.
For electronic descalers, the evidence is inconsistent. Some studies have shown reduced scale adhesion on laboratory heating surfaces; real-world domestic results vary considerably. Which? magazine tests and independent consumer reports suggest some users see benefits, others none. The Drinking Water Inspectorate does not endorse electromagnetic descalers, and no independent body has certified them as equivalent to ion-exchange softening.
Polyphosphate dosing has more consistent evidence for reducing scale deposition on heating elements, which is why it is used in some commercial boiler protection systems. It is not, however, whole-house softening.